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© Thomson Reuters, Journal Citation Reports, 2017

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© Clarivate Analytics, Journal Citation Reports 2017

Bol Soc Esp Ceram Vidr 2018;57:142-50 - DOI: 10.1016/j.bsecv.2017.10.007
Production of vitreous materials from mineral coal bottom ash to minimize the pollution resulting from the waste generated by the thermoelectrical industry
Producción de materiales vítreos a partir de escoria de carbón mineral para reducir la contaminación producida por los residuos generados por la industria termoeléctrica
Camila da Silva Gonçalvesa,, , Adriano Michael Bernardinb, Rozineide Aparecida Antunes Boca Santaa, Cassio Leonia, Geraldo Jorge Mayer Martinsa, Claudia Terezinha Kniessc, Humberto Gracher Riellaa
a Chemical Engineering Department, Santa Catarina Federal University, P. O. Box 476, Trindade, 88.040-900 Florianópolis, SC, Brazil
b Santa Catarina Extreme South University, 88.806-000 Criciúma, SC, Brazil
c University Nove de Julho, 05001-000 São Paulo, SP, Brazil
Recibido 26 junio 2017, Aceptado 24 octubre 2017
Abstract

Mineral coal bottom ash exerts a great impact on the environment due to the presence of heavy metals in its composition and the lack of an adequate area for disposal. Vitreous materials were synthesized from bottom ash to be employed as a by-product. The bottom ash was subjected to an X-ray fluorescence (XRF) analysis to evaluate the oxide composition present in the material. To study the effect of bottom ash in the attainment of glass, a simplex lattice design for experiments with blends was employed. The elements considered in the design were: bottom ash; sodium carbonate (Na2CO3) and calcium oxide (CaO), both used as melting agents; magnesium oxide (MgO), which was used as a stabilizer for the vitreous network. For the characterization of the glasses, X-ray diffraction (XRD), differential scanning calorimetry (DSC) and Fourier transform infrared spectrometry (FTIR) were carried out. Ten different formulations were tested. The results indicated that two out of the ten formulations formed a crystalline phase, which is undesirable for a vitreous material. In the statistical analyses, the Pareto Diagram and the response surface showed that the glass transition and softening temperatures were strongly influenced by the level of calcium oxide and magnesium oxide, as well as that of bottom ash, resulting in an increase in the softening and glass transition temperatures.

Resumen

La escoria de carbón mineral afecta profundamente al medio ambiente por la existencia de metales pesados en su composición y la falta de un área adecuada para su eliminación. Los materiales vítreos se sintetizaron a partir de escoria para ser empleados como subproducto. La escoria se sometió a un análisis de fluorescencia de rayos X (XRF) para evaluar la composición de óxido presente en el material. Para estudiar el efecto de la escoria en la obtención de vidrio, se empleó un diseño de malla simple para experimentos con mezclas. Los elementos que se valoraron en el diseño fueron: escoria; carbonato de sodio (Na2CO3) y óxido de calcio (CaO), ambos utilizados como agentes de fusión; óxido de magnesio (MgO), que se utilizó como estabilizador de la red vítrea. Para la caracterización de los vidrios se llevaron a cabo difracción de rayos X (XRD), calorimetría de barrido diferencial (DSC) y espectrometría de infrarrojos por transformada de Fourier (FTIR). Se probaron 10 formulaciones diferentes. Los resultados indicaron que 2 de las 10 formulaciones formaron una fase cristalina, que es indeseable para un material vítreo. En los análisis estadísticos, el diagrama de Pareto y la superficie de respuesta mostraron que la transición vítrea y las temperaturas de reblandecimiento estaban muy influidas por el nivel de óxido de calcio y de óxido de magnesio, así como por el de escoria, lo que aumentaba las temperaturas de reblandecimiento y transición vítrea.

Keywords
Mineral coal, Solid waste, Bottom ash, Pollution, Glasses
Palabras clave
Carbón mineral, Desechos sólidos, Escoria, Contaminación, Vidrios
Introduction

The coal-based thermoelectrical energy sector is an activity with large impact on the environment [1]. Mineral coal is one of the most employed resources throughout the world for energy production. Despite being a potentially polluting fuel, coal will probably continue leading as a source of energy generation [1]. According to the International Energy Agency and the World Coal Association [2], the combustion of mineral coal currently contributes with about 30% of the global primary energetic needs. The current coal reserves are estimated to be enough to meet the global production for approximately 150 years [2,3].

A crucial problem presented by mineral coal in thermoelectric is the generation of industrial waste, among which are tons of bottom ash and fly ash [4]. Fly ash are particles which move with the combustion gas as it leaves the furnace, while bottom ash are the particles which sediment at the furnace's bottom [5]. Bottom ash is considered one of the main industrial by-products [6]. The growing generation of ashes has long been source of environmental, technological and economic problems around the world [7]. According to data from the American Coal Ash Association (ACAA), in 2014 approximately 12 million tons of bottom ash were produced, and only 12% of those were subsequently used [8]. Given this context, the low frequency of utilization of this residue justifies the scarce existing research on the use of bottom ash [9].

Most technical and environmental problems associated with the use of mineral coal arise due to its inorganic components, especially the non-combustible ones [10]. According to Kim [11], the composition of bottom ash is basically constituted of SiO2 (53.5%), Al2O3 (23.9%) and an acidic/basic oxides ratio of 2:1. The composition of the two ashes is practically the same, but the bottom ashes have more moisture [8], and larger particle size. According to Ulusoy and Igathinathane [12], particle size distribution is an important measurement of the physical characteristics of ash, exerting influence in various aspects concerning its utilization, such as heat and mass transfer, as well as homogeneity of its mixture with other components.

In this context, this research was elaborated to evaluate the potential of bottom ash obtained in the south region of Santa Catarina, Brazil, to be used as the main raw material in the production of glasses, thus minimizing the environmental impacts and obtaining new materials with added value. An experimental design for mixtures was utilized to constitute 10 glasses using sodium carbonate and a 2:1 mixture of CaO/MgO, respectively, as melting agents. The effects of each component in the thermal properties of the glasses were determined.

The sodium-calcium glasses were prioritized for this study because they comprise 90% of all glass produced on Planet Earth [13], that is, the demand for these materials is extremely high.

The large proportions of SiO2 found in bottom ash form the glass phase, and the alumina (Al2O3) acts as an intermediate cation, making the chemical bond more stable with oxygen, increasing the viscosity of the medium and acting as modifiers when the medium is favorable [14].

Few researches are available on the application of bottom ash in the production of glasses. Choi and Kang [15], for instance, investigated the degree of surface crystallization and the crystallization mechanism for SiO2–Al2O3–Li2O glasses containing coal bottom ash. Kim and Kang [16] studied TiO2 additions on the crystallization kinetics of a coal bottom ash Li2O glass system. The main publications found with bottom ash are pertaining to ceramic and glass ceramic materials, cements, composites, among others. Contrastingly, this study deals with the synthesis and characterization of a material that is little explored in terms of publications.

Experimental procedureAsh preparation

To withdraw moisture and facilitate its milling, bottom ash went through oven drying at 105°C for 24h. After the drying stage, the bottom ash was milled in a ball mill, model CS-501K, for 24h under a rotation of 65rpm and with alumina balls of 10, 14 and 17mm.

To identify the oxides present in the material, a gray sample was collected for X-ray fluorescence analysis (XRF).

Preparation of the formulations

For the preparation of the formulations an experimental planning for mixtures, simplex-lattice type, was employed. Bottom ash, being an industrial waste and presenting a large composition, was considered a pseudo-component. CaO and MgO melting agents were used in the ratio of 2:1, respectively. Na2CO3 was used as the source of Na2O, and the loss of CO2 during melting was taken into account in the calculation of the proportions, as shown in Table 1. The melting agents employed have a high degree of analytical purity.

Table 1.

Experimental formulation for 100g of glass sample.

Samples  BA  Na2CO3  CaO/MgO 
78.0  25.0  7.3 
58.5  58.4  7.3 
53.3  22.8  33.3 
65.0  47.3  7.3 
61.1  23.5  25.2 
55.0  33.9  25.2 
71.5  36.1  7.3 
69.3  24.2  16.5 
56.7  45.8  16.5 
10  63.0  35.0  16.5 

The resulting glasses were annealed at a temperature of 5°C above the Tg for 4h, then cooled slowly to room temperature. Characterization analyses were performed under the annealed glass.

Table 1 shows the experimental formulation for a 100g glass sample.

Fusion for the acquisition of the glass samples

The formulations were melted in a Schally oven (model LAB – S 5.6) at a temperature between 1480 and 1500°C utilizing alumina crucibles, with volume of 70mL. The crucibles containing each mixture were inserted in the oven, where they remained for 4h until the complete fusion of the components, with a maximum melting temperature varying between 1480 and 1500°C. At the end of the 4h, the contents in the crucibles were poured in a metallic mold for the attainment of glasses.

Characterization techniques

To identify the presence of crystalline phases, the X-ray diffraction (XRD) technique was employed. The analyses were performed via the powder method in a Philips X’Pert diffractometer with CuK α, radiation (1.5418Å). The parameters of the analysis were: acceleration of 40kV and 30mA, 2θ interval of 3 to 118° and a step of 0.02°s−1. The JCPDS database was utilized for the identification of the samples.

To characterize the mineral coal bottom ash, the X-ray fluorescence (XRF) technique, model Philips PW2400, was employed. For the execution of the assay, a bottom ash sample was pressed in a double layer with a base of boric acid, H3BO3 (Merck base), with a pressure of 5 tons for 10s in a tablet shape. The tablet was then analyzed in an X-ray fluorescence spectrophotometer with a wavelength dispersion sensor (WDS).

The glasses underwent thermal analysis through the differential scanning calorimetry (DSC/TG) technique. The device utilized was a STA 449 F3 Jupiter model, from Netzsch. The essay conditions were: a temperature interval from 20 to 1200°C with a heating rate of 20°Cmin−1 and synthetic air atmosphere with a flux of 5mlmin−1, situated in high alumina crucibles. The temperatures of glass transition (Tg), softening (Ts) and crystallization (Tc) were obtained by the first derivation method, i.e., as this temperatures are kinetic events, the first derivative on the DSC curve was used and the Tg or Ts were determined as the major peaks on the derivative curves for each glass composition. The Netzsch Proteus® software was used to accurately determine Tg and Ts.

The Fourier Transform Infrared Spectroscopy (FTIR) technique was employed to analyze the behavior of the bonds between Si–O, Al–O, Mg–O, Ca–O, Na–O and Fe–O in the vitrification of the materials studied. The device utilized was an infrared spectrophotometer from Shimadzu, model IR Prestige 21. The sample was mixed to KBr in the ratio of 1% sample to 99% KBr by volume.

Results and discussionXRF analysis of bottom ash

Table 2 shows the chemical elements present in the composition of mineral coal bottom ash. The components, identified by the XRF technique (Table 2) take part in the process of the acquisition of glass in different shapes. The elevated silicate percentage, for instance, justifies the employment of ash as a source material for the glass network.

Table 2.

Composition in oxides of the bottom ash under study.

Oxide  (% mass) 
SiO2  53.3 
Al2O3  22.9 
Fe2O3  15.1 
K23.1 
CaO  2.1 
TiO2  1.3 
MgO  0.7 
Na20.5 
MnO  0.1 
P2O5  0.1 
Loss to fire  0.5 

Alumina, according to Navarro [14] and Harper [17] increases the chemical durability and the mechanical resistance. The iron oxide acts mainly as a dye, providing a black color (for high iron levels) or yellow color (for smaller iron quantities) to the material [18].

Titanium oxide, as stated by Varshneya [19], acts as a nucleating agent, favoring the emergence of crystals during the thermal treatment process of the crystallization.

The calcium, sodium and potassium oxides act as fusion agents and are fundamental in the production of glass. The melting agents are compounds which, when added to the glass net, decrease the melt temperature, viscosity and glass transition temperature [20]. They are mostly alkali metal oxides and act as network modifiers. Modifications in glass properties are due to loss of connectivity, transforming a covalent oxygen bond into ionic and can provide extra oxygen ions, increasing the Si/O ratio in the glass [21].

Potassium oxide, according to Navarro [14], interferes in the composition of the glass when present in amounts lower than 1.0% and given that the bottom ash contains 3.1% of K2O. Compared to sodium oxide, potassium oxide increases the viscosity of the glass and increases its thermal range of work.

Sodium oxide (NaO) acts to reduce the viscosity of the glass, favoring its softening temperature; the cation has great affinity with oxygen, which in turn breaks its bond with silica and binds to sodium, causing a break in the net. Excess sodium in the formulation, however, renders the material soluble in water [22].

Calcium binds to the oxygen by breaking the bonds between oxygen and silica, and, because of their bivalence, each calcium atom binds to two oxygen atoms. Since it generates a new bond for every two bonds destroyed, calcium is not as efficient as sodium in reducing the softening temperature, but given its poor solubility in water, it becomes more resistant to solubility [23]. Calcium oxide in proportions greater than 46.0% in the vitreous composition does not act as a network modifier, forming Ca–O–Ca, while the majority of the calcium cations occupies CaO6 distorted octahedra surrounded by chains of SiO4 tetrahedra [24].

Magnesium oxide acts as a network stabilizer, lowering the dilation coefficient and increasing the resistance to thermal shock [14].

Particle size distribution

Fig. 1 presents the size distribution of the bottom ash particles in natura after oven drying for 24h at 105°C.

Fig. 1.
(0.05MB).

Size distribution of the bottom ash particles.

The bottom ash presented a greater quantity of passing particles in the 50 mesh (0.297mm), which totalled 24.5% of the particles. The size of interest is the 200 mesh (0.074mm), but only 4.8% of the particles presented this diameter. Such fact justified the milling of the product in order to reduce particle size and guarantee a better homogeneity of the vitreous mixture.

Physical characteristics of the glasses formed

Fig. 2 illustrates the glasses obtained from bottom ashes based on the experimental design.

Fig. 2.
(0.38MB).

Formed glasses. Formulation 3 (a), formulation 5 (b), formulation 8 (c) and formulation 9 (d).

The materials obtained exhibited the characteristics of a glass, such as high brightness (not measured). Their brittle aspect was a consequence of being poured on a cold surface, thus generating tractive tensions on the external side and compressive ones in the interior of the vitreous droplet. This problem can be bypassed with the thermal treatment of annealing for tension relief, which consists in inserting the poured vitreous piece in an oven at a low temperature. Fig. 2 presents the formed glass without undergoing any heat treatment, thus justifying the presence of cracks.

Most glasses present identical physical characteristics, hampering their differentiation without the use of characterization techniques or adequate devices. However, some samples differed from the rest, e.g. sample 9, which presented a certain opacity, a characteristic that makes glasses esthetically undesirable. Sample 9 presented different physical characteristics compared the other glasses. As verified in the XRD technique, this material formed crystalline phases, not characterizing it as glass. Its composition presents 45.8% of sodium carbonate or, if neglecting the CO2, 26.8% of NaO. The sample also presented a high content of CaO and MgO (11.0% and 5.5%, respectively), oxides which are crystalline structure builders. Sodium reduces the viscosity of the vitreous medium, increasing the mobility of crystals and the crystallization tendency. Crystallization can be defined as the process by which a stable solid phase forms from a structurally disordered phase, resulting in a geometric ordering of the structure [25]. This process occurs because the vitreous substances have lower stability than the crystalline phase, with an energetic content greater than thermodynamic equilibrium. Thus, when subjected to favorable conditions, there is a reduction of the free energy of the system, which leads to the formation of crystalline structures [14].

Bottom ash has in its composition a nucleating agent, TiO2, which accelerates the nucleation process even in small quantities [26]. Thus, the composition of the ash and the proportions of the oxides used in the sample 9 exerted great influence on its crystallization. It can also be stated that a similar process occurred with sample 2.

XRD analyses of the glasses

The diffractograms of samples 1, 3, 4, 5, 6, 7, 8 and 10 were considered amorphous and are shown in Fig. 3. The absence of well defined peaks denotes the disordered structure of the samples, which is typical of the glasses. Samples 2 and 9 exhibited typical peaks of the crystal structures (Fig. 4a and b). Peak identification was performed using the High Score PAnalytical software, according to JCPDS.

Fig. 3.
(0.31MB).

Diffractograms identified for the samples 1, 3, 4, 5, 6, 7, 8 and 10.

Fig. 4.
(0.12MB).

Diffractograms identified for glasses 2 and 9.

The diffractograms of the samples 2 and 9 show the formation of well defined peaks in the region of 2θ=21, 35, 50 and 62°, identified as (A): NaAlSiO4 (JCPDS 01-076-0909), (B): Fe2SiO4 (JCPDS 01-083-1654), (C): Fe2O3 (JCPDS 01-084-0311), (D): Na2Mg2Si2O7 (JCPDS 00-053-0626).

Analysis obtained through the DSC technique

DSC/TG analyses were performed for the 10 glass samples. Table 3 and Fig. 5 present the results obtained.

Table 3.

Glass transition (Tg), softening (Ts) and crystallization (Tc) temperatures obtained by the first derivation method by DSC.

Samples  Tg (°C)  Ts (°C)  Tc (°C) 
579  1094  817 
726  1060  – 
631  1046  – 
505  1002  567–605 
613  1078  931 
574  1100  766 
537  1104  832 
598  1151  978 
579  1187  1127 
10  571  1137  712 
Fig. 5.
(0.2MB).

Graphs of differential scanning calorimetry (DSC) technique for samples 1–10.

It is important to emphasize that the exothermic peaks (Fig. 5) are associated to devitrifications, indicating a tendency of crystallization for the formed glasses.

The formation of crystalline phases for glasses 2 and 9, confirmed by the absence of peaks, altered the thermal behavior during the DSC analysis. Glasses 2 and 9 did not clearly show a transition in glass, a typical feature of vitreous materials. However, since the DSCs showed a discrete transition of the thermal behavior associated with a Tg region, it is possible that the vitreous systems have formed ceramic eyeglass frames. This is a consequence of rapid crystallization due to the higher CaO/MgO content and the presence of TiO2 in the compositions. For the crystallization of the species – SiO2, MgO, CaO – it is necessary that the system presents mobility for the formation of the coordination polyhedron. The low viscosity contributes to the increase of ion mobility and is related to the higher proportion of Na2O. For the formation of crystals, crystallization nuclei must initially be formed, that is, they need a stable surface, because at high temperature all the glass is a fluid. TiO2 acts as a nucleating agent and is a stable center for crystal growth.

Statistical analysis

In this work, the most important parameters were the glass transition (Tg) and softening (Ts) temperatures, considering the statistical analysis. As the aim of the work was to develop a suitable glass formulation for an industrial application, the lower temperatures were considered as the most adequate for energy saving during the glass melting process. Therefore, the effects that the factors (bottom ash, sodium carbonate and calcium oxide/magnesium oxide contents) exert on the characteristic temperatures (system response) were analyzed.

For a confidence interval of 95%, the quadratic model was the most significant for the Tg results and the linear model was the most significant for the Ts results. Only the main factors A, B and C (standing for bottom ash, Na2CO3 and CaO/MgO, respectively) were significant in the response regarding the glass transition temperature and the softening point. The Pareto diagrams (Fig. 6 and Fig. 7, respectively) show these results.

Fig. 6.
(0.11MB).

Pareto diagram for Tg.

Fig. 7.
(0.12MB).

Pareto diagram for Ts.

The Pareto diagram for the glass transition temperature (Tg) shows that the amount of CaO/MgO was the most important factor in order to increase the Tg, followed by the bottom ash content and the Na2CO3 content. The results are shown as the ‘standardized effects estimate’ in ‘absolute values’, which means the size of the effect of a given response, no matter its unit. That is, for the glass transition temperature, the amount of CaO/MgO and bottom ash are the parameters which show the greatest influence on the Tg results regarding the size of the effect, not on the value of the glass transition temperature.

Regarding the softening temperature, the Pareto diagram (Fig. 7) shows the same trend as for the glass transition temperature. The amount of CaO/MgO was the most significant factor to increase the softening temperature, followed by the amount of bottom ash and the amount of Na2CO3. For the Ts, the Pareto chart shows that all the three parameters are very significant regarding the 95% confidence interval. The degree of significance for both Tg and Ts is 0.997, meaning a confidence of 99.7%.

The response surface for the glass transition temperature, Fig. 8, shows that the lowest Tg are achieved when the amount of Na2CO3 is increased in the glass formulation. The Na2CO3 brings Na2O to the structure of the silica glass, a strong modifier that raises the number of non-bridging oxygen and therefore weakens the glass structure. The bottom ash alone raises the Tg due to its chemical composition, mainly SiO2, a glass former, and Al2O3, also a glass former when in tetrahedral coordination. CaO and MgO also raise the Tg. This is due the valence of each ion, Ca2+ and Mg2+ cause a lower reduction in the bonding energy of the silica glass (Si4+ and Al3+) than the Na+ ions. Regarding the Pareto chart, the CaO/MgO amount causes a stronger effect on Tg due to the size effect, but not in the decrease of the glass transition temperature. This effect is probably due to the addition of Na+ ions to the glass compositions in the form of a carbonate (Na2CO3), and not as a pure oxide like the CaO/MgO mixture.

Fig. 8.
(0.1MB).

Response surface graph for Tg.

For the softening temperature (Ts), Fig. 9, the effect of the amount of Na2O is stronger than in the glass transition temperature (Tg) and its size effect, given by the Pareto chart (Fig. 6) is like the size effect of the other raw materials (bottom ash and CaO/MgO). The CaO/MgO addition strongly raises the softening temperature, while the bottom ash has an intermediate effect. The amount of bottom ash used in this study – 78.0 to 53.3% – was probably just enough to form the glass structure, indicating that the amount of CaO/MgO is in excess, thus raising the bonding energy. But this is only an assumption, since NMR studies are needed to give the speciation of the O (bridging and non-bridging) and Si ions in the glass structure.

Fig. 9.
(0.1MB).

Response surface graph for Ts.

FTIR analysis performed on the glasses

Fig. 10 shows the results of the FTIR analysis performed in the ten samples of synthesized glasses.

Fig. 10.
(0.25MB).

FTIR for the ten glass samples.

In every specter (Fig. 10), three regions can be distinguished, each characterized by absorption maxima due to different types of vibration:

  • (a)

    950–1200cm−1, represent stretching vibrations of Si–O–Si and Si–O–M (M=A1, Mg, Fe) [27].

  • (b)

    1460–1500cm−1, represent stretching vibrations of carbonation (CO3) [28,29], probably due to atmospheric contamination, since the decarbonation process occurs around 850°C.

  • (c)

    3450–3670cm−1, the bands between 3450 and 3670cm−1 are attributed to the stretching of OH [30]. The identified OH group has the same origin as CO2, i.e., the water identified in this analysis comes from environmental contamination.

Conclusion

The attainment of glass from bottom ash was viable and completely satisfactory, since the raw material employed is considered a residue, which if not utilized can become an environmental problem due to its careless disposal in the environment.

The XRD analyses showed that, out of the ten formulations tested, only two did not form glasses, but crystals; both differed from the rest in the color and the brightness (opaque) of the piece. For the crystalline samples, one phase was identified for Glass 2 (NaAlSiO4) and three for Glass 9 (NaAlSiO4, Fe2O3 and Fe2SiO4). The crystallization occurred in glasses with a low content of bottom ash (58.5 and 56.7%) and melting agents (41.5 and 43.3%), mainly NaO, which decreases the viscosity of the medium and favors the mobility of the ions, thus increasing the tendency of forming crystals. The presence of TiO2 in the bottom ash composition favored the formation of crystals, since this oxide is a nucleating agent.

The DSC analyses showed that the vitreous mixtures melt at temperatures below 1500°C, which is due to the effect of the melting agents. Pure bottom ash melts at a much higher temperature, evidencing thus an energy economy, in addition to improving the properties of the material. The lowest softening temperature was observed in Glass 4 (65.0% bottom ash, 47.3% Na2CO3 and 7.3% CaO/MgO), which was 1002°C and the highest in Glass 8 (69.3% bottom ash, 24.2% Na2CO3 and 16.5% CaO/MgO), this being 1151°C. In the TG analysis, no loss of mass of the obtained materials was evidenced. In addition, the DSC analysis showed that all the glasses of the formulation exhibited exothermic peaks, indicating a tendency to crystallize the samples. The absence of peaks was shown for already crystallized samples.

According to the statistical analysis, the raw materials exerted a great influence on both the softening (Ts) and glass transition (Tg) temperatures, in which CaO/MgO fluxes followed by bottom ash were the factors that most contributed to their growth. The presence of sodium oxide decreased Tg and Ts. CaO/MgO caused a lower reduction of the vitreous bond energy when compared to NaO, which in turn is the most influent factor in the glass transition and softening temperatures.

FTIR analyses ascertained the existence of the probable elements present in the glass samples, evidencing the Si–O and Si–O–M (M=A1, Mg, Fe) bonds, stretching vibrations of carbonation (CO3) and OH vibrations, the two latter being considered contamination by the external environment.

Acknowledgments

The authors wish to thank Tractebel Energy and UFSC for the support in this research.

References
[1]
Plano Nacional de Energia, 2030: Geração termoelétrica: carvão mineral, 2007.
[2]
World Coal Association. Available from: https://www.worldcoal.org/.
[3]
L. Bartoňová
Unburned carbon from coal combustion ash: an overview
Fuel Process. Technol., 134 (2015), pp. 136-158
[4]
M. Rafieizonooz,J. Mirza,M.R. Salim,M.W. Hussin,E. Khankhaje
Investigation of coal bottom ash and fly ash in concrete as replacement for sand and cement
Constr. Build. Mater., 116 (2016), pp. 15-24
[5]
Eletric Power Research Institute, Coal Ash: characteristics, management and environmental issues, EPRI Report 1019022, September, 2009.
[6]
S.S.G. Hashemi,H.B. Mshmud,J.N.Y. Djobo,C.G. Tan,B.C. Ang,N. Ranjbar
Microstructural characterization and mechanical properties of bottom ash mortar
J. Clean., 170 (2018), pp. 797-804
[7]
M. Erol,S. Kuçukbayrak,A. Ersoy-Meriçboyu
Characterization of coal fly ash for possible utilization in glass production
Fuel, 86 (2007), pp. 706-714
[8]
American Coal Ash Association (CAAA), Coal ash production, use survey 2014, News Conference – Washington, D.C., American Coal Ash Association (CAAA), Coal ash production and use survey 2014, News Conference – Washington DC, 2015. Available from: https://www.acaa-usa.org/Portals/9/Files/PDFs/2014-Production-and-Use-Survey-Presentation.pdf.
[9]
R.A.A. Boca Santa,C. Soares,H.G. Riella
Geopolymers obtained from bottom ash as source of aluminosilicate cured at room temperature
Constr. Build. Mater., 157 (2017), pp. 459-466
[10]
F.E. Huggins
Overview of analytical methods for inorganic constituents in coal
Int. J. Coal Geol., 50 (2002), pp. 169-214
[11]
H.K. Kim
Utilization of sieved and ground coal bottom ash powders as a coarse binder in high-strength mortar to improve workability
Constr. Build. Mater., 91 (2015), pp. 57-64
[12]
U. Ulusoy,C. Igathinathane
Particle size distribution modeling of milled coals by dynamic image analysis and mechanical sieving
Fuel Process. Technol., 143 (2016), pp. 100-109
[13]
M. Akerman
Introdução ao vidro e sua produção
ABIVIDRO – Escola do Vidro, (2013)
[14]
J.M.F. Navarro
El vidrio
3 ed, Consejo Superior de Investigaciones Científicas, (2003)
[15]
C. Choi,S. Kang
Crystallization behavior at nucleation sites on the surfaces of vitreous materials loaded with coal bottom ash
J. Korean Phys. Soc., 54 (2009), pp. 1320-1324
[16]
W. Kim,S. Kang
Processing research influence of TiO2 additions on the crystallization kinetics of a coal bottom ash-Li2O glass system
J. Ceram. Process. Res., 11 (2010), pp. 557-560
[17]
C.A. Harper
Handbook of Ceramics, Glasses and Diamonds
McGraw-Hill, (2001)
[18]
C.T. Kniess,N.C. Kuhnen,H.G. Riella,E. Neves,C.D.G. Borba
Estudo do efeito da quantidade de óxido de ferro em cinzas pesadas de carvão mineral na obtenção de vitrocerâmicos
Quim. Nova, 25 (2002), pp. 926-930
[19]
A.K. Varshenya
Fundamentals of Inorganic Glasses
Academic Press, Inc., (1994)
[20]
Y.M. Chiang,P.D. Birnie,W.D. Kingery
Physical Ceramics: Principles for Ceramic Science and Engineering
1st ed., John Wiley & Sons, (1997)
[21]
J. Zarzycki
Les verres et l’état vitreux
Manson, (1982)
[22]
L. Fugita
Utilização de selênio como colorante/descolorante em vidros sodo-cálcicos
EPUSP, (2004)
[23]
M. Akerman
Natureza, estrutura e propriedades do vidro
(2000)
[24]
D.S. Meneses,M. Malki,P. Echegut
Optical and structural properties of calcium silicate glasses
J. Non-Cryst. Solids, 352 (2006), pp. 5301-5308
[25]
W. Höland,G. Beall
Glass-ceramics Technology
The American Ceramics Society, (2002)
[26]
Z. Strnad
Glass-ceramic Materials
Elsevier, (1986)
[27]
M.A. Karakassides
An infrared reflectance study of Si–O vibrations in thermally treated alkali-saturated montmorillonites
Clay Miner., 34 (1999), pp. 429-438
[28]
E. Arioz,O. Arioz,O.M. Kockara
Leaching of F-type fly ash based geopolymers
Proc. Eng., 42 (2012), pp. 1114-1120
[29]
I. Lancellotti,M. Cannio,F. Bollino,M. Catauro,L. Barbieri,C. Leonelli
Geopolymers: an option for the valorization of incinerator bottom ash derived “end of waste”
Ceram. Int., 41 (2015), pp. 2116-2123
[30]
B.J. Saikia,G. Parthasarathy
Fourier transform infrared spectroscopic characterization of kaolinite from Assam and Meghalaya, Northeastern India
Int. J. Mod. Phys., 1 (2010), pp. 206-210
Corresponding author. (Camila da Silva Gonçalves goncalvesscamila@gmail.com)
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