Application in chromium (VI) removal of natural and dried cactus

Sakr, F.; Sennaoui, A.; Dinne, M.; Alahiane, S.; Bakas, I.; Belmoden, M.; Assabbane, A.

doi:10.1016/j.ctmat.2018.01.001

Article information

Abstract

Download PDF

Statistics

Abstract

This research presents two type of cactus (Opuntia ficus-indica) (natural cactus (NC) and dried cactus (DC)) as a biological adsorbent, evaluated for the effectiveness of hexavalent chromium Cr(VI) removal from artificially contaminated aqueous solutions. The characterization of the biosorbents were made using different techniques such as X-ray Fluorescence (XRF), Fourier transform infrared (FTIR) and Scanning Electron Microscope (SEM) to better understand the adsorption mechanism-property relationship. Adsorption kinetics showed that the adsorption behavior followed the pseudo-second-order kinetic model. The adsorption isotherms fitted by the Langmuir model showed that the highest Cr(VI) adsorption capacities using natural cactus and dried cactus are 21.19 and 2.63mg/g respectively. Additionally, various physiochemical parameters such as contact time, adsorbent dosage, pH and temperature were investigated in a batch-adsorption technique. The results illustrated that the cactus have significant potential as economic, safe and effective adsorbent materials for the Cr(VI) adsorption from the aqueous solution.

Keywords:

Adsorption

natural cactus

dried cactus

hexavalent chromium

biosorbent

isotherms

kinetic

Full text is only available in PDF

References

[1]

A.K. Shanker, C. Cervantes, H. Loza-Tavera, S. Avudainayagam.

Environ. Int, 31 (2005), pp. 739

[2]

K.J. Cronje, K. Chetty, M. Carsky, J.N. Sahu, B.C. Meikap.

Desalination, 275 (2011), pp. 276

[3]

B. Saha, C. Orvig.

Coord. Chem. Rev, 254 (2010), pp. 2959

[4]

Z. Zainul Akmar, S. Marlini, M. Nurfadilah, A. Wan Azlina.

Desalination, 244 (2009), pp. 109

[5]

R.Y. Taj, S. Renganathan, N. Partha, G. Baskar, M. Velan.

Clean - Soil, Air, Water, 37 (2009), pp. 787

[6]

D. Sarkar, S.K. Das, P. Mukherjee, A. Bandyopadhyay.

Clean - Soil, Air.

Water, 38 (2010), pp. 764

[7]

P.S. Kumar, S. Ramalingam, R.V. Abhinaya, S.D. Kirupha, A. Murugesan, S. Sivanesan.

Clean - Soil Air Water, 40 (2012), pp. 188

[8]

S. Chen, Q. Yue, B. Gao, Q. Li, X. Xu, K. Fu.

Bioresour. Technol, 113 (2012), pp. 114

[9]

K. Mohanty, M. Jha, B.C. Meikap, M.N. Biswas.

Chem. Eng. J, 117 (2006), pp. 71

[10]

J.N. Sahu, J. Acharya, B.C. Meikap.

J. Hazard. Mater, 172 (2009), pp. 818

[11]

J. Rodier, B. Legube, N. Merlet.

Coll..

L’analyse de l’eau, 9ème edition, Dunod, (2009),

[12]

F.T. Li, H. Yang, Y. Zhao, R. Xu.

Chinese Chem. Lett, 18 (2007), pp. 325

[13]

N.V. Farinella, G.D. Matos, M.A.Z. Arruda.

Bioresour. Technol, 98 (2007), pp. 1940

[14]

J.V. Ibarra, R. Moliner.

J. Anal. Appl. Pyrolysis, 20 (1991), pp. 171

[15]

N. Barka, K. Ouzaouit, M. Abdennouri, M. Makhfouk.

J. Taiwan Inst. Chem. Eng, 44 (2013), pp. 52

[16]

D. Park, S.R. Lim, Y.S. Yun, J.M. Park.

Bioresour. Technol, 99 (2008), pp. 8810

[17]

B. Mahjoub, I. Fkih, M.C. Nacibi. Élimination du chrome hexavalent des solutions aqueuses par adsorption sur feuilles brute de de Posidonia oceanica (L.): cinétiques, équilibres et modélisation, Déchets - Revue francophone d’écologie industrielle, Sousse, 2009, pp. 19-26.

[18]

M.J. Sarre, M. Mazet.

Rev. Sci. Eau, 1 (1988), pp. 55

[19]

N. Daneshvar, D. Salari, S. Aber.

J. Hazard. Mater, B94 (2002), pp. 49

[20]

A. Asfaram, M. Ghaedi, G.R. Ghezelbash.

RSC Adv, 6 (2016), pp. 235999

[21]

M.C. Ncibi, B. Mahjoub, M. Seffen.

J. Hazard. Mater, B139 (2007), pp. 280